Definition of Portmanteau Words in English

A portmanteau word is a word formed by merging the sounds and meanings of two or more other words. More formally known as a blend. The term portmanteau word  was coined by English writer Lewis Carroll in Through the Looking-Glass, and What Alice Found There (1871). Later, in the preface to his nonsense poem  The Hunting of the Snark (1876), Carroll offered this explanation of Humpty-Dumptys theory of two meanings packed into one word like a portmanteau: [T]ake the two words fuming and furious. Make up your mind that you will say both words, but leave it unsettled which you will say first. Now open your mouth and speak. If your thoughts incline ever so little towards fuming, you will say fuming-furious; if they turn, by even a hairs breadth, towards furious, you will say furious-fuming; but if you have the rarest of gifts, a perfectly balanced mind, you will say frumious. Examples and Observations: Brangelina (Brad Pitt Angelina Jolie)bromance (brother romance)Cronutâ„ ¢ (croissant doughnut)dramedy (drama comedy)Frankenfood (Frankenstein food)infomercial (information commercial)motel (motor hotel)netiquette (net etiquette)Oxbridge (Oxford Cambridge)pixel (pic element)quasar (quasi-stellar star)sexpert (sex expert)sexting (sex texting)smog (smoke fog)splatter (splash spatter)statusphere (status atmosphere)Tanzania (Tanganyika Zanzibar)telethon (television marathon)Viagravation (Viagra aggravation)A word formed by fusing elements of two other words, such as Lewis Carrolls slithy from slimy and lithe. He called such forms portmanteau words, because they were like a two-part portmanteau bag. Blending is related to abbreviation, derivation, and compounding, but distinct from them all.(Tom McArthur, Blend. The Oxford Companion to the English Language. Oxford University Press, 1992) The Sound Bites of Modern English [D]ancercise, simulcast, Frappuccino  Ã¢â‚¬â€Ã‚  they wear their meanings on their shortened sleeves. Portmanteau words are the sound bites of modern English, calculated to catch on the first time people hear them.(Geoffrey Nunberg, The Way We Talk Now. Houghton Mifflin, 2001)Smirting happens when two people, smoking outside, fall to flirting, and discover that they have more in common than simply nicotine. In Ireland, where the term originated after the ban in 2004, there is even evidence of non-smokers joining the smoky throng outside because the atmosphere there is more flirtatious.Smirting is a portmanteau word, formed by packing parts of two words together to create another, combining the sense of each.(Ben Macintyre, Ben Macintyre Celebrates the Portmanteau. The Times, May 2, 2008) Portmanteau Survivors:Dumbfound, Flabbergasted, Gerrymander Portmanteau words are frequently more whimsical than useful and dont survive, but many exist. ...  Dumbfound, from dumb and confound, was put together in the 17th century. Flabbergasted, one of the more contrived, is apparently an 18th-century blend of flabby and aghast. Gerrymander combines the name of Governor Elbridge Gerry and salamander, referring to the shape of a redistricted Massachusetts county. Anecdotage, adding the implication of dotage to anecdote, and Clifton Fadimans hullabalunacy from hullabaloo and lunacy, are clever enough to deserve survival.(Robert Gorrell, Watch Your Language!: Mother Tongue and Her Wayward Children. University of Nevada Press, 1994) Portmanteau Games Two games can be played with portmanteau words. In the first game, one player thinks of a portmanteau word and asks the next player to say which words are blended to create it. In the second game, players try to make up new, humorous portmanteau words and give their definitions. Thus you might blend the words hen and endurance to make hendurance, meaning the patience of a hen trying to hatch out an egg. Or you could blend the name of the dog Rin-tin-tin (who starred in films) and the word tintinnabulation to get Rin-tin-tintinnabulation: a very loud ringing of bells.(Tony Augarde, The Oxford A to Z of Word Games. Oxford University Press,1994) The Lighter Side of Portmanteau Words So a blog is a web log? Is there an apostrophe, or do you guys not even have the strength for that? You’re just going to jam two words together?(Stephen Colbert, The Colbert Report, Feb. 2006)In her first tweet, [Sarah] Palin didnt write speak out; she used another term  Ã¢â‚¬â€Ã‚  refudiate. A few minutes later, the Tweet was rewritten with refudiate  Ã¢â‚¬â€Ã‚  which is not actually a word —  removed,  replaced by refute. ...The word caught someones attention, because a few hours later Palin refused to refute refudiate, she tweeted that shes just following in Shakespeares footsteps.Refudiate, misunderestimate, wee-weed up. English is a living language. Shakespeare liked to coin new words too. Got to celebrate it!(Carolyn Kellogg, Wherefore Art Thou, Refudiate? Sarah Palin as Shakespeare. Los Angeles Times, July 19, 2010) Pronunciation: port-MAN-tow Also Known As: blend

Health Care Provision Of The Affordable Care Act - 1948 Words

Within the past couple of year, the United States as a whole has had challenges with improving the overall population health. The increase in healthcare costs has caused a distinct disparity within minority groups. Under the Affordable Care Act, cost and access has drastically affected many individuals. Despite the United States increase in spending, many are still uninsured and vulnerable to detrimental health outcomes. The uninsured have no access to sufficient and effective health care services, meaning they resort to little or no care at all. For example, different racial and minority groups are without access to Medicaid and Medicare due to its restrictions. Targeted groups such as African Americans and Hispanics have lower rates of health care coverage, access and overall quality of care. It is evident that minorities were misrepresented among the coverage provisions of the Affordable Care Act. Apart from such target groups, whites appear to receive better health care coverage and outcomes. This has become a problem when it comes to health care access, meaning there are major health discrepancies. There is a disparity gap between the different ethnic groups that the Affordable Care Act fails to accurately address and provide provisions to such requirements for government-funded assistance programs (Shi Singh, 2015). U.S Population and Implications Within the United States, the demographics continually show that the nation is become more racially and culturallyShow MoreRelatedHealth Care Of The United States1594 Words   |  7 Pagespast few decades, health care industry in the United States is facing three major problems related to quality, costs, and access. The healthcare expenditure in the United States has increased drastically over the years and the United States still rank top in health care spending when compared to other top nations in the world. Despite having high healthcare expenditure, Americans have limited access to health care, spends higher costs for the procedures and getting poor health care outcomes. In a recentRead MoreHealthcare And Health Care Industry824 Words   |  4 Pagesthe past few decades health care industry in United States is facing three major problems related to quality, costs and access. The health care expenditure in United States has increasing drastically over the years and United stat es still ranks top in health care spending when compared to other top nations in the world. Despite of having high health care expenditure, Americans have limited access to health care, spends higher costs for the procedures and getting poor health care outcomes. In a recentRead MoreInstitutional Affiliation : Health Care Reform Essay1392 Words   |  6 Pages Health Care Reforms Student’s Name Institutional Affiliation Health Care Reforms Introduction Health services are the most apparent purpose of any health system both to the general public and the user. Service provision points to the way input the likes of money, staff drugs and equipment are linked to facilitate the delivery of health requirements. Health services incorporate all services that deal with the diagnosis and treatment of an ailment or the maintenance, promotion, and restorationRead MoreKey Provisions of the Affordable Care Act1571 Words   |  7 Pages The Affordable Care Act or â€Å"Obamacare† was designed to assure that all Americans regardless of health status have access to affordable health insurance. The Affordable Car Act was signed into law March 23, 2010. The primary goal of this act was to decrease barriers for obtaining health care coverage and allow Americans to access needed health care services (Affordable Care Act Summary, n.d). After the legislation is fully implemented in 2014, all Americans will be required to have health insuranceRead MoreHealthcare : A Complex Healthcare System Essay919 Words   |  4 PagesManaged Care is a complex healthcare system in which physicians, hospitals, and other healthcare professionals organize in an interrelated system of people and facilities that communicate with one another and work together as a unit, commonly referred to as a network. This network coordinates and arranges healthcare services and benefits for a specific group of individuals, referred as enrollees, for the purpose of managing cost, quality, and acess to healthcare. Managed care program may be providedRead MoreThe Impact Of Affordable Care Act On Supply And Demand1063 Words   |  5 PagesThis paper will look at the impact of Affordable Care Act on supply and demand in healthcare. The goal is to show if there is equilibrium of supply and demand since the Affordable Care Act was enacted. This has been done by looking at a variety of articles such as The Impact of the Affordable Care Act on the Health Care Workforce. The Affordable Care Act has created provisions to address some of the supply shortages. Through the provision it will take time for the full effects to come to lightRead MoreAffordable Care Act ( Aca )875 Words   |  4 PagesAffordable Care Act Understanding the Affordable Care Act (ACA) can be problematic, the goal of the ACA is to address the fact that millions of Americans do not have health insurance, yet they are contributors to the health care market, consuming health care services for which they do not pay. While this may seem to be a great idea, many Americans are not really sure how they are affected by this Health Care Reform. The goal is to make health insurance affordable, secure, and reliable for all. Read MoreContemporary Health Care Issue: The Affordable Care Act1397 Words   |  6 PagesContemporary Health Care Issue: The Affordable Care Act Mary Kennedy Grand Canyon University HCA 530 Healthcare Policies and Economics Professor Steve Klense Contemporary Health Care Issue: The Affordable Care Act Introduction More than 45 million Americans are uninsured. Even those that do have health insurance often face financial and other barriers when getting healthcare. The Affordable Care Act (ACA) removes most of these financial barriers (Kocher, Emanuel, amp; DeParle, 2010). TheRead MoreThe Debate Over the Constitutionality of the Affordable Care Act818 Words   |  3 Pagespeople to buy health insurance has been highly advocated by the supporters, and highly scrutinized by the opposition. The constitutionality of the Patient Protection and Affordable Care Act of 2010 has thus been defended on both sides. Advocates argues why it is constitutional by providing reason and benefits of the Act, and the opposition argues why it is not constitutional by providing reason, and stating the drawbacks of the Act. The debate about the Constitutionality of the Act boils down toRead MoreEssay about Hca 305 Week 2 Assignment1625 Words   |  7 PagesPATIENT PROTECTION amp; AFFORDABLE CARE ACT OF 2010 (P.P.A .C.A.) HCA305: The U.S. Health Care System Instructor Delana Chappell-James January 14, 2013 PATIENT PROTECTION amp; AFFORDABLE CARE ACT OF 2010 (P.P.A.C.A.) Introduction If there is one thing that most Americans are in agreement with, it is the vile shape of our U.S. health care system. There is no argument that the U.S. health care system is in need of an overhaul, however, there is much debate over just how to effectively

Snow Falling on Cedars - 1700 Words

Men with authority in Snow Falling on Cedars possess great power and can manipulate an outcome based on their own personal bias. Horace Whaley’s racist qualities emerge from their patriotism and experiences in war. Horace Whaley, a coroner, is a Caucasian American who served his country in war. His patriotism and experience in war allows him to become a close-minded and racist individual, â€Å"Horace had served as a medical officer for twenty months in the Pacific theater and had suffered in that period from sleep deprivation and from a generalized and perpetual tropical malaise that had rendered him, in his own mind, ineffective† (Guterson 46). After the morning recess, Horace Whaley swears softly on the courtroom bible and edges his name†¦show more content†¦In this particular case, Guterson provides information about Horace Whaley, including his painful and traumatic experiences of this psychological pain. This unpleasant experience communicates a negative response, since the cause of Horace’s psychological trauma will result in deep hatred towards that certain cause, in Horace’s case his services in war against foreigners. Psychoanalytical theory is applicable in this scenario under Horace’s deep resentment towards Japanese individuals. Horace’s harsh experiences resulted in the development of resentment of Japanese individuals. Horace directs resentment towards the Japanese since they were the cause of his pain and sense of shame that he attained in war. Accordingly, Horace develops behavioural manifestations of an indirect sense of vengeance. Horace’s contains aggressive wishes towards the Japanese man on trial, seen in his opposing position on the trial. Thus, the negative implications imposed on Horace through the environmental experiences of war have formulated his distinct hatred towards the individuals responsible for his trauma. Horace’s involvement in the war led to the development o f his racist qualities coupled with his patriotism, â€Å"Horace indicated for Art Moran the blood that had clotted in the dura mater and the tear in it where the piece of brain protruded. ‘He got hit pretty hard with something fairly flat, Art. Puts me in mind of aShow MoreRelated Snow Falling on Cedars Essay702 Words   |  3 Pages Throughout the film ‘Snow Falling on Cedars’ the director Scott Hicks has used symbolism to convey a number of his ideas. He used the fog and snow to symbolise hidden secrets, the sea to represent life and death, and he used the Cedars to symbolise a place of secrecy and protection. By using these three symbols, Scott Hick’s ideas could be conveyed without anything being said at all. Fog and snow are used in the film to symbolise hidden secrets and to convey the idea that nothing can stay hiddenRead More Snow Falling On Cedars Essay1052 Words   |  5 Pagesrange from a simple comment to make another human being feel inferior, to complex actions that make others feel unwelcome in society because of who they are. The theme of racism can be seen throughout literature. In the murder mystery novel, Snow Falling on Cedars, by David Guterson, many examples of wartime racism are evident. The novel is set on San Piedro Island off the coast of Washington in the year 1954. It is a place of â€Å"five thousand damp souls† (5). Kabuo Miyamoto, a member of the islandsRead More Critical Response to David Gutersons Snow Falling on Cedars1247 Words   |  5 PagesCritical Response to David Gutersons Snow Falling on Cedars David Gutersons novel Snow Falling on Cedars undoubtedly holds high acclaim in its reputable attempt to show the prejudice between the Americans and Japanese after World War II and more importantly the prejudice that is unavoidably apart of human nature. The author of the criticism recognizes and brings to light the things done by Guterson throughout the novel. He refers to the animosity between people brought about by differences,Read More Difficult Choices in David Guterson’s Snow Falling on Cedars1976 Words   |  8 PagesDifficult Choices in David Guterson’s Snow Falling on Cedars It is mid 1950’s in predominantly white populated San Piedro Island. One of its residents has been murdered and another stands accused of the crime. From the first chapter and through the use of flashbacks, David Guterson makes us aware of the racism that exists in the small, West Coast island of San Piedro. The victim, Carl Heine, is of European descent; the accused man, Kabuo Miyamoto, is of Japanese ancestry. There also is a smallRead More Racial Prejudice in David Gutersons Snow Falling on Cedars Essay1791 Words   |  8 PagesRacial Prejudice in David Gutersons Snow Falling on Cedars Its not one ocean, said Hatsue. Its four oceans...Theyre different from each other. Well how are they different? They just are. (Guterson 97). Snow Falling on Cedars, David Gutersons award winning novel, is set on an island in Puget Sound in the early 1950s. It is a story of the racial prejudice that was felt so strongly against Japanese Americans immediately before, during and after WWII. Kabuo Miyamoto,Read MoreLantana and Snow Falling on Cedars906 Words   |  4 PagesLantana and Snow Falling on Cedars present a variety of relationships that explore the restrictions of characters in a culturally limiting society, and ones with intertwining emotions and secrets that contain a darker reality. The crucial type of relationship in both texts is the forbidden connections that are abundant with unrealistic expectations, developed through characterisation as the plot progresses. The texts also display the relationships that have become dysfunctional after significantRead More Snow Falling on Cedars Essay1129 Words   |  5 PagesSnow Falling on Cedars Everyone has experienced prejudice sometime in their life. It has been an undeniable force in society ever since history was recorded. Even the most open-minded people and enlightened organizations can be blamed as being prejudice sometime or another. However, prejudice always takes its toll from these people who form opinions beforehand or without any facts. The novel, Snow Falling On Cedars, take place during a time in which Americans are prejudice towards JapaneseRead MoreSnow Falling on Cedars Essay897 Words   |  4 Pagesis powered by an individual’s determination and will. The use of the word â€Å"chambers† echoes directly with three major themes of the text, these being; the chambers of the heart, the chambers of the judge’s courthouse, and also the chambers of the cedar tree where Hatsue and Ishmael consummate their love. The final sentence has great importance to the text as it shows Ishmael understands that he will always love Hatsue however he w ill never be able to know her hearts desires, and should thereforeRead MoreConflicting Perspectives - Snow Falling on Cedars993 Words   |  4 Pagesperspectives eventuating in conflict with another. These ideals are represented through the character construction and narrative style displayed in David Gutterson’s â€Å"Snow Falling On Cedars† and the filmic version of Harper Lee’s â€Å"To Kill a Mockingbird† directed by Robert Mulligan. Body: A key character in â€Å"Snow Falling on Cedars† who represents the ideals of bias and self-interest affecting ones perspective is Etta Heine. Etta Heine’s character has been constructed to represent the strong socialRead MorePrejudice And Discrimination In Snow Falling On Cedars2253 Words   |  10 PagesHow does Guterson present the prejudice and discrimination against the Japanese Americans in chapter 1-15 of Snow Falling on Cedars. This book shows a great difference between cultures on the island of San Piedro. To start with the island is a very cosmopolitan island with its residents all from different backgrounds and countries, Japan, England, Germany, Spain and Denmark to name a few. We can tell this from the long lists of shops and their owners on page three. Chapter one tells us more about

Charter Schools Is The Best - 940 Words

For nearly a decades, charter schools have become the modern rival of public schools, but does the charter schools is the best? In modern society, people keep chasing the American dream; they want to achieve better life quality and higher education. As most people believe, education is a primarily way to train children all the skills which will need as adults to find good jobs and live well, but the nation have many different types of schools, such as private schools, charter schools, home schools, or traditional public schools. Therefore, when a kid is old enough to start going to school, it’s also a tough time for parents to make a decision to choose type of education system which they trust enough to hand over the children’s future. According to a source, when compare to traditional public school, although some of charter schools were â€Å"successful†, some were â€Å"troubled and struggling†, but most of them were â€Å"somewhere in between just lik e traditional public schools.†(Grace) .Therefore, in my opinion, the government should not convert all public schools to charter schools because charter school itself still exists some issues which may make education becomes worse, such as inconformity in school management system, under-performing in comparison to public schools, and teachers’ experiences. The significant issue of charter schools is the inconformity in school management system. Because of the freedom and autonomy, this makes charter schools are difficult to manage orShow MoreRelatedCharter Schools Are The Best Schools1608 Words   |  7 PagesCharter schools offer much more than public schools do, like smaller classrooms and extended one-on-one time. Charter schools are â€Å"independent entities that have received a charter, which is a set of self-written rules (and promises) about how the school will be structured and run† (Pascual, 2016, The Truth About Charter Schools). This means that they have their own rules that work for the children and meet their individual needs. The schools could change the rules, as generations change, to accommodateRead MoreCharter Schools vs. Public Schools Essay1341 Words   |  6 PagesCharter Schools vs. Public Schools Are charter schools the right choice to the educational needs of our children? Charter schools are tuition free public schools created and operated by parents, organizations, and community groups to fill student’s educational needs. Charter schools consider educating their students as the priority, and identify how children’s learning needs are different from each other, so they came up with different ways on educating their students such as learning in small groupsRead MoreWhy Charter Schools Are Important to Education Essay example1415 Words   |  6 Pages Why Charter Schools Are Important to Education Charter schools are public schools, but can be a better option than traditional public schools for some students. By definition, a charter school is a publicly funded and privately run school under the charter of an educational authority. (2-4) A charter school is held to a different set of standards than most traditional public schools. This can often work towards their advantage because it allows them to try new and unique methods of educating childrenRead MoreEssay about Charter Schools: A Feasible Solution?1311 Words   |  6 PagesCharter Schools This is the issue of Charter Schools. Charter Schools simultaneously funded by nonprofit corporations, guided, by founded research, innovative and creative, yes, fun teaching methods, positive academic rewards and fascinating field trip excursions. Successful charter schools upheld the standards of quality and created the most optimal learning environment for the emerging minds of the future. These assessments describe the academic ability of the students enrolled. Since theRead MoreCharter Schools Are Better Than Public Schools885 Words   |  4 PagesCHARTER SCHOOLS ARE BETTER THAN PUBLIC SCHOOLS? Education is a very important part of a person’s life. Every parent want the best thing for their children. They want their children to be happy and to be able to achieve their dreams and be what they want to be, which is why they want the best education for their children. Because, almost everyone would agree that being well – educated is the closest way to success life and good future. But, their desire to send their kids to the best school haveRead MorePublic School And Why Should They Be Kept993 Words   |  4 PagesTreiber 02/20/2015 Public School and Why Should They Be Kept Among many things that involve in education, schools have stood out as the most important reason that people, especially parents, care and take great effort in researching. â€Å"The best school† has been an issue wondering in parents’ mind whether public or charter school should be the right place for their children, for this will be the starting point that may determine the future of their precious â€Å"angels†. Charter schools have stood out to mostRead MoreEssay about Charter Schools1318 Words   |  6 PagesCharter schools are an alternative to public schools. Whether this alternative is a better solution to the public schools is the argument. Public schools can be just as creative as charter schools. Public schools are funded by our tax dollars, which ultimately the United States Government decides where those funds go. Education should be the last thing to be cut in the budget, but unfortunately, we the people do not have a choice other than the public offices whom we hope will do what they have saidRead MoreCharter Schools Essay1610 Words   |  7 PagesCharter Schools: The Future of Education? For decades the American education system provided parents with three choices: public, homeschool or private school. If they chose public then their child(ren) would be assigned to a school past on where they lived. However , â€Å"in the early 1990s a handful of states created independent public charter schools, providing opportunities for teachers and others to develop innovative schooling options â€Å" (Palmer, Louann 2007). Not only did the creation ofRead More Public Education Essay1454 Words   |  6 Pagespublic schools are still failing to provide students with a quality education. This is disheartening as we learn that the United States lags behind in math and science compared to our international counterparts. It is safe to say that educational reform has spent billions of dollars over the years in an honest effort to reform education in American; however, most reform decisions have produced little changes. Among the many radical education reform strategies implemented, charter schools are perhapsRead MoreThe Opinion Of Charter Schools1687 Words   |  7 Pages As I began working on this essay, my first step was to google charter school news articles. One of the first two articles that I came across was from a well known conservative news source. The other was published in a prominent outlet for liberal news. I was amazed at the polar opposite views that the two sources had on the subject and decided to see if this dichotomy continued in other news outlets as well. I then looked up a ranking of various news sources as liberal or conservative. I

Power in Shakespeare Free Essays

Power has significantly marked the society where we are in current development. Power is one of the best ways to control a society, yet it impacts the society in a negative way when it comes to distributing rights and opportunities. That is, since it involves the worst issues within the government known as corruption. We will write a custom essay sample on Power in Shakespeare or any similar topic only for you Order Now In William Shakespeare’s play, Richard III, and Aristophanes’ play, Lysistrata, both authors employ the major role and concept of power. Both Shakespeare’s and Aristophanes’ approach to power has influenced the understanding of power and through their examples; one can employ their ideas as to why sometimes I feel powerless or powerful in my current life of a student. The views expressed by these authors are focused politically to power, which make people reflect on what power means; this involves attraction and subjugates provocation. The power is so great that it will always be seen negatively. With power one can organize groups but, there needs to be an authority. For example, like those with the political, economic, military or religious power. Yet, the problem comes when the abuse of power arises and when having too much power, the mind can be corrupted. It is necessary that one should have a good posture when power comes into hand and one should see it as something to improve on rather than to enhance on the small things that one does not need. Power should be seen as the ability to control to do the right thing and for that reason, be able to accomplish positive changes for the rest of the community. As a student, one has the ability to have power or not to have power either by sitting in a regular classroom or being at the university in general. At the university, there are laws, rules and authority that needs to be followed and for that reason a student could sometimes feel powerless. For instance, there is a rule at FAU that a student can’t be absent from a class for a certain amount of days. The student is able to feel powerful because he or she has the ability to not go to class. Yet, once he or she reaches or passes the amount of days, the student will be automatically dropped out and in addition will receive a penalty for it. So a student can feel powerless because it has no other choice but to go to the class just so he or she wouldn’t get penalized. In other words, one could explain how different styles of power could have similar characteristics through the norms and rules that exist today. For example, the power exerted from a government of any country must be abided by the people who inhabit it through compliance ith the same laws and standards. Also, the student of any university must also follow the same rules and laws established by the university. As you can see, this example represents a power running scheme of a major and minor scale, but with a similar goal, which is how to maintain order where there is always power. The penalty is always the consequence, that is, if you decide to take too much power into your own hands. If one has power, he or she should be able to manipulate it well enough to not let it go into the wrong hands. Similarly in Richard III, Shakespeare employs Hastings as a lord with honor who always remains loyal and trustworthy to the family. But when he gives all his trust and all his power to Richard, Richard ends up killing him. With power comes a consequence, and coinciding to this idea, that is why with power, corruption always occur. To that reason, a student will feel powerless because he or she has no other choice but to attend class. In order to be able to advance and be successful in class, you have to depend on your surroundings rather than self-advancement. One should be able to find peers and ask them what they did the whole class. Also, one is able to get the notes and basically get everything of what the teacher did without being in class. This being said, a student will feel powerful only if they have their surroundings by the palm of their hand. If the student is going to use his or her power, it will need to depend on its surroundings in order to be able to get the power that he or she wants. As said by Shakespeare, â€Å"Which done, God take King Edward to his mercy, and leave the world for me to bustle in, for then I’ll marry Warwick’s youngest daughter† (5). At school, one cannot depend on himself or herself, but on the teacher and on the peers. In Shakespeare view, he is showing how Richard views his power and Richard needs his surroundings and his superiority in order to get to King Edward’s throne. As for Aristophanes, Lysistrata would have never been able to succeed if she did not have the help of the other women. Her use of manipulation helped her gain power and she was able to take back her man and bring peace to the city. In addition, manipulating is being able to handle, control, or use someone or something cleverly and skillfully for one’s own advantage. A student can exercise the power to manipulate other students not to follow the rules or establish academic programs. Students who do not have responsibility and honesty are able to induce other students not to follow their school schedule, for example the student’s class attendance. The student’s friends will tell them to not attend class, go to the beach, or miss class just to miss it. And likewise, they are able to decrease the academic level in their classes because they assume no responsibility and maturity with the commitment to remain in a serious institution such as a university. These students still depend on their parents and since they know their parents will pay everything for them, they get low self-esteem and they won’t be able to value themselves and appreciate what they have. For this reason, they are people who have no responsibility and have no commitment when it comes to effort and it will be reflected once they attend the university. Therefore, that is why they influence other students to do the same. Aristophanes explains how the women were able to manipulate the power and strength of their husbands and warriors, exerting some manipulation of their womanhood and wife. Similarly, Shakespeare speaks of Elizabeth’s power over King Edward. By then, Richard is seeing the king as being weak and being handled by women. â€Å"Why, this it is, when men are ruled by women; my Lady Grey his wife, Clarence, ‘tis she that tempers him to this extremity† (Shakespeare 3). Comparing the previous texts, a student to a certain extent, can manipulate by being able to respect and enforce the university rights. For example, receiving an academic background in the area specified and chosen by the student and freely expressing its ideas and not being able to get punished because of them. This is why universities should take responsibility to train professionals and specialists in various areas of knowledge, as well as the formation of authentic citizens with moral and ethical responsibilities committed to the social reality around them. In Lysistrata, the women had a hard time being heard by the town and similarly, I have that same problem with my life as a college student. Just as the commissioner said in Lysistrata, â€Å"you expect me to take orders from a woman. I’d die first† (Aristophanes 91). The men during that era did not take the women into consideration and they were never taken into account. They were always ignored and predominated the power of men. Aristophanes portrayed the women into another new level by giving them the importance that they needed. Although they were only valued as a house wife, Aristophanes took into consideration how important sex is in the life of men, and gave power to the women using their ingenuity. Due to the fact that FAU has a great amount of tudents not only in the school in general but in the classes as well, the professors cannot provide a personalized education for each student. For that reason, that is why students sometimes feel ignored. It is very complicated for a professor to dictate a class with an abundance of students and the time assigned by the university because it limits them to give just a general class. In the other hand, it is not the professor’s fault but it is the university’s in general as to why most students are ignored. It is up on our time to go to the professor’s office hours just to have a conversation from person to person. People usually ask what they have to do in order to get to power while having the connections and influences and at the same time being a normal and ordinary person. For me, the answer or explanation to this question is due to my presence here at Florida Atlantic University because it is obtained through preparation, school work, and knowledge. For that reason, there is a famous phrase said by nearly everyone today that â€Å"knowledge is power†. Yet, through the knowledge that I gain, I have the ability and power to make my own decisions. How to cite Power in Shakespeare, Papers Power in Shakespeare Free Essays Power has significantly marked the society where we are in current development. Power is one of the best ways to control a society, yet it impacts the society in a negative way when it comes to distributing rights and opportunities. That is, since it involves the worst issues within the government known as corruption. We will write a custom essay sample on Power in Shakespeare or any similar topic only for you Order Now In William Shakespeare’s play, Richard III, and Aristophanes’ play, Lysistrata, both authors employ the major role and concept of power. Both Shakespeare’s and Aristophanes’ approach to power has influenced the understanding of power and through their examples; one can employ their ideas as to why sometimes I feel powerless or powerful in my current life of a student. The views expressed by these authors are focused politically to power, which make people reflect on what power means; this involves attraction and subjugates provocation. The power is so great that it will always be seen negatively. With power one can organize groups but, there needs to be an authority. For example, like those with the political, economic, military or religious power. Yet, the problem comes when the abuse of power arises and when having too much power, the mind can be corrupted. It is necessary that one should have a good posture when power comes into hand and one should see it as something to improve on rather than to enhance on the small things that one does not need. Power should be seen as the ability to control to do the right thing and for that reason, be able to accomplish positive changes for the rest of the community. As a student, one has the ability to have power or not to have power either by sitting in a regular classroom or being at the university in general. At the university, there are laws, rules and authority that needs to be followed and for that reason a student could sometimes feel powerless. For instance, there is a rule at FAU that a student can’t be absent from a class for a certain amount of days. The student is able to feel powerful because he or she has the ability to not go to class. Yet, once he or she reaches or passes the amount of days, the student will be automatically dropped out and in addition will receive a penalty for it. So a student can feel powerless because it has no other choice but to go to the class just so he or she wouldn’t get penalized. In other words, one could explain how different styles of power could have similar characteristics through the norms and rules that exist today. For example, the power exerted from a government of any country must be abided by the people who inhabit it through compliance ith the same laws and standards. Also, the student of any university must also follow the same rules and laws established by the university. As you can see, this example represents a power running scheme of a major and minor scale, but with a similar goal, which is how to maintain order where there is always power. The penalty is always the consequence, that is, if you decide to take too much power into your own hands. If one has power, he or she should be able to manipulate it well enough to not let it go into the wrong hands. Similarly in Richard III, Shakespeare employs Hastings as a lord with honor who always remains loyal and trustworthy to the family. But when he gives all his trust and all his power to Richard, Richard ends up killing him. With power comes a consequence, and coinciding to this idea, that is why with power, corruption always occur. To that reason, a student will feel powerless because he or she has no other choice but to attend class. In order to be able to advance and be successful in class, you have to depend on your surroundings rather than self-advancement. One should be able to find peers and ask them what they did the whole class. Also, one is able to get the notes and basically get everything of what the teacher did without being in class. This being said, a student will feel powerful only if they have their surroundings by the palm of their hand. If the student is going to use his or her power, it will need to depend on its surroundings in order to be able to get the power that he or she wants. As said by Shakespeare, â€Å"Which done, God take King Edward to his mercy, and leave the world for me to bustle in, for then I’ll marry Warwick’s youngest daughter† (5). At school, one cannot depend on himself or herself, but on the teacher and on the peers. In Shakespeare view, he is showing how Richard views his power and Richard needs his surroundings and his superiority in order to get to King Edward’s throne. As for Aristophanes, Lysistrata would have never been able to succeed if she did not have the help of the other women. Her use of manipulation helped her gain power and she was able to take back her man and bring peace to the city. In addition, manipulating is being able to handle, control, or use someone or something cleverly and skillfully for one’s own advantage. A student can exercise the power to manipulate other students not to follow the rules or establish academic programs. Students who do not have responsibility and honesty are able to induce other students not to follow their school schedule, for example the student’s class attendance. The student’s friends will tell them to not attend class, go to the beach, or miss class just to miss it. And likewise, they are able to decrease the academic level in their classes because they assume no responsibility and maturity with the commitment to remain in a serious institution such as a university. These students still depend on their parents and since they know their parents will pay everything for them, they get low self-esteem and they won’t be able to value themselves and appreciate what they have. For this reason, they are people who have no responsibility and have no commitment when it comes to effort and it will be reflected once they attend the university. Therefore, that is why they influence other students to do the same. Aristophanes explains how the women were able to manipulate the power and strength of their husbands and warriors, exerting some manipulation of their womanhood and wife. Similarly, Shakespeare speaks of Elizabeth’s power over King Edward. By then, Richard is seeing the king as being weak and being handled by women. â€Å"Why, this it is, when men are ruled by women; my Lady Grey his wife, Clarence, ‘tis she that tempers him to this extremity† (Shakespeare 3). Comparing the previous texts, a student to a certain extent, can manipulate by being able to respect and enforce the university rights. For example, receiving an academic background in the area specified and chosen by the student and freely expressing its ideas and not being able to get punished because of them. This is why universities should take responsibility to train professionals and specialists in various areas of knowledge, as well as the formation of authentic citizens with moral and ethical responsibilities committed to the social reality around them. In Lysistrata, the women had a hard time being heard by the town and similarly, I have that same problem with my life as a college student. Just as the commissioner said in Lysistrata, â€Å"you expect me to take orders from a woman. I’d die first† (Aristophanes 91). The men during that era did not take the women into consideration and they were never taken into account. They were always ignored and predominated the power of men. Aristophanes portrayed the women into another new level by giving them the importance that they needed. Although they were only valued as a house wife, Aristophanes took into consideration how important sex is in the life of men, and gave power to the women using their ingenuity. Due to the fact that FAU has a great amount of tudents not only in the school in general but in the classes as well, the professors cannot provide a personalized education for each student. For that reason, that is why students sometimes feel ignored. It is very complicated for a professor to dictate a class with an abundance of students and the time assigned by the university because it limits them to give just a general class. In the other hand, it is not the professor’s fault but it is the university’s in general as to why most students are ignored. It is up on our time to go to the professor’s office hours just to have a conversation from person to person. People usually ask what they have to do in order to get to power while having the connections and influences and at the same time being a normal and ordinary person. For me, the answer or explanation to this question is due to my presence here at Florida Atlantic University because it is obtained through preparation, school work, and knowledge. For that reason, there is a famous phrase said by nearly everyone today that â€Å"knowledge is power†. Yet, through the knowledge that I gain, I have the ability and power to make my own decisions. How to cite Power in Shakespeare, Essay examples

Biography Of Franklin Delano Roosevelt Essay Example For Students

Biography Of Franklin Delano Roosevelt Essay Word Count: 1630Roosevelt was born at his familys estate at Hyde Park, in Dutchess County, New York on January 30,1882. He was the only child of James Roosevelt and Sara Delano Roosevelt. James Roosevelt was a moderately successful businessman, with a variety of investments and a special interest in coal. He was also a conservative Democrat who was interested in politics. His home overlooking the Hudson River was comfortable without being ostentatious, and the family occupied a prominent position among the social elite of the area. Sara Delano, 26 years younger than her previously widowed husband, brought to the marriage a fortune considerably larger than that of James Roosevelt. The Delano family had prospered trading with China, and Sara herself had spent some time with her parents in Hong Kong. So, Franklin was born into a pleasant and sociable home, with loving wealthy parents. Roosevelts parents sent him off to school in 1896. They selected Groton School in Massachusetts, which had a reputation as one of the finest of the exclusive private schools that prepared boys for the Ivy League colleges. Young Roosevelt was a good student, popular with his fellow students as well as with his teachers. Roosevelt moved to New York City, where he entered the Columbia University Law School in 1904. Although he attended classes until 1907, he failed to stay on for his law degree after passing the state examinations allowing him to practice law. For the next three years he was a clerk in a prominent law firm in New York City, but the evidence is clear that he had little interest in law and little enthusiasm to be a lawyer. Well before he finished his work at Columbia, young Franklin Roosevelt had married his distant cousin Anna Eleanor Roosevelt. They had been in love for some time and were determined to marry in spite of the opposition of Franklins mother. The brides uncle, President Theodore Roosevelt, was present at the ceremony in New York City on March 17, 1905. Five of their six children grew to maturity: Anna, James, Elliott, Franklin, Jr., and John. The chief problem faced by the young couple during the early years of their marriage was Sara Roosevelts possessive attitude toward her son. Eleanors forbearance mitigated this situation, but the problem remained for many years. Roosevelt entered politics in 1910, when he became a candidate for the New York State Senate in a district composed of three upstate farming counties. Democratic leaders had approached young Roosevelt because of his name and local prominenceand because he might be expected to pay his own election expenses. The 28-year-old Roosevelt campaigned hard, stressing his deep personal interest in conservation and other issues of concern in an agricultural area and also his strong support of honest and efficient government. In the first good year for Democrats since the early 1890s he was narrowly elected. He was only the second Democrat to represent his district after the emergence of the Republican Party in 1856. In the state capitol at Albany, Roosevelt gained statewide publicity as the leader of a small group of upstate Democrats who refused to follow the leadership of Tammany Hall, also known as the Tammany Society, the Democratic Party organization of New York City. In particular, they refused to vote for the rich politician William F. Blue-Eyed Bill Sheehan for U.S. senator. Roosevelts group succeeded in blocking the election of Sheehan, which infuriated Tammany Hall. The dramatic struggle drew the attention of New York voters to the tall vigorous new state senator with the magic name of Roosevelt. He soon became a dedicated social and economic reformer, and a political independent. He was reelected in 1912, in spite of a case of typhoid fever that kept him from campaigning. .uc93cd21bca90fddb5b0b0cef361cb9ce , .uc93cd21bca90fddb5b0b0cef361cb9ce .postImageUrl , .uc93cd21bca90fddb5b0b0cef361cb9ce .centered-text-area { min-height: 80px; position: relative; } .uc93cd21bca90fddb5b0b0cef361cb9ce , .uc93cd21bca90fddb5b0b0cef361cb9ce:hover , .uc93cd21bca90fddb5b0b0cef361cb9ce:visited , .uc93cd21bca90fddb5b0b0cef361cb9ce:active { border:0!important; } .uc93cd21bca90fddb5b0b0cef361cb9ce .clearfix:after { content: ""; display: table; clear: both; } .uc93cd21bca90fddb5b0b0cef361cb9ce { display: block; transition: background-color 250ms; webkit-transition: background-color 250ms; width: 100%; opacity: 1; transition: opacity 250ms; webkit-transition: opacity 250ms; background-color: #95A5A6; } .uc93cd21bca90fddb5b0b0cef361cb9ce:active , .uc93cd21bca90fddb5b0b0cef361cb9ce:hover { opacity: 1; transition: opacity 250ms; webkit-transition: opacity 250ms; background-color: #2C3E50; } .uc93cd21bca90fddb5b0b0cef361cb9ce .centered-text-area { width: 100%; position: relative ; } .uc93cd21bca90fddb5b0b0cef361cb9ce .ctaText { border-bottom: 0 solid #fff; color: #2980B9; font-size: 16px; font-weight: bold; margin: 0; padding: 0; text-decoration: underline; } .uc93cd21bca90fddb5b0b0cef361cb9ce .postTitle { color: #FFFFFF; font-size: 16px; font-weight: 600; margin: 0; padding: 0; width: 100%; } .uc93cd21bca90fddb5b0b0cef361cb9ce .ctaButton { background-color: #7F8C8D!important; color: #2980B9; border: none; border-radius: 3px; box-shadow: none; font-size: 14px; font-weight: bold; line-height: 26px; moz-border-radius: 3px; text-align: center; text-decoration: none; text-shadow: none; width: 80px; min-height: 80px; background: url(https://artscolumbia.org/wp-content/plugins/intelly-related-posts/assets/images/simple-arrow.png)no-repeat; position: absolute; right: 0; top: 0; } .uc93cd21bca90fddb5b0b0cef361cb9ce:hover .ctaButton { background-color: #34495E!important; } .uc93cd21bca90fddb5b0b0cef361cb9ce .centered-text { display: table; height: 80px; padding-left : 18px; top: 0; } .uc93cd21bca90fddb5b0b0cef361cb9ce .uc93cd21bca90fddb5b0b0cef361cb9ce-content { display: table-cell; margin: 0; padding: 0; padding-right: 108px; position: relative; vertical-align: middle; width: 100%; } .uc93cd21bca90fddb5b0b0cef361cb9ce:after { content: ""; display: block; clear: both; } READ: The Great Gatsby Symbolism EssayEven before his reelection to the New York legislature, Roosevelt had entered the national political arena by taking part in the campaign of Governor Woodrow Wilson of New Jersey for the Democratic nomination for president. Once again the young state senator was a member of a minority group among New York Democrats. When Wilson won at both the convention and the polls in 1912, his early supporters were rewarded, and Roosevelt became assistant secretary of the United States Navy. Roosevelt resigned his state senate seat and moved to Washington, D.C., to take over the position once occupied by his cousin Theodore Roosevelt. Franklin Roosevelts years as assistant secretary, from 1913 to 1920, taught him both how to get things accomplished and, just as important for an executive, how to avoid unnecessary trouble. He had the devoted assistance of Louis Howe, who came along to the nations capital as Roosevelts assistant. Roosevelts superior was Secretary of the Navy Josephus Daniels, a North Carolina editor. Daniels was a close friend and devoted follower of Nebraska editor and former Representative William Jennings Bryan, three times the Democratic candidate for president and Wilsons secretary of state. Like Bryan, Daniels was concerned about agrarian issues and was a progressive reformer. He was also an isolationist (someone who believed that the United States should avoid alliances with other nations), who hated the idea of war. Young Roosevelt, an energetic supporter of a bigger navy and soon a warm friend of most of the leading admirals, inevitably had many disagreements with his chief, especially duri ng Wilsons first term. Daniels had the confidence both of the president and of the most influential Democrats in the Congress of the United States; Roosevelt had neither of these. However, in time the two men came to have genuine respect for one anothers different talents, and they remained good friends. Personal tragedy struck Roosevelt in August 1921, when he contracted what was diagnosed, after an unfortunate delay, as poliomyelitis. He had been plagued by illness of various sorts during the previous decade, and he had overexerted himself swimming and hiking at Campobello. In great agony and completely unable to walk, Roosevelt seemed to have reached the end of his active public career. Indeed, his mother wanted him to return to Hyde Park for the peace and quiet of the life of a country gentleman. However, backed by the determination of his wife and Louis Howe, Roosevelt decided to return to his work as soon as possible. In spite of the efforts of numerous specialists and of his strenuous exercises, particularly swimming at his second home in Warm Springs, Georgia, he was never again able to walk unaided. He spent most of his working hours in a wheelchair, and he walked with leg braces and canes, usually with help. Through the worst years of his paralysis, Roosevelt was amazingly cheerful. Eleanor Roosevelt often acted as her husbands eyes and ears, bringing him information and conferring with people he was no longer readily able to meet. Howe remained close by Roosevelt, assisting him in many ways and planning for his return to public life. Roosevelt continued to busy himself with Democratic politics after his illness. And in 1928 Roosevelt made a run for the Governor of New York, and won by a narrow margin. In October 1929 the economic prosperity that the United States had enjoyed for most of the 1920s came to an abrupt end. Following the stock market crash of October 1929 Roosevelt found himself a depression governor, with new problems to face. In 1930 he was reelected by the unprecedented number of 725,000 votes. In 1932 there was a presidential election and Roosevelt got the Democratic nomination, but had a tough time doing it. Roosevelt had more difficulty in winning the Democratic nomination in 1932 than he had in defeating President Hoover. In spite of Hoovers unprecedented efforts to use the power of the federal government to overcome the Great Depression, he was completely identified with the policies of former U.S. presidents Warren Harding and of Calvin Coolidge, since he had served as secretary of commerce in both administrations. Roosevelts task was essentially a simple one: to convince the American people that because the Republicans had claimed full credit for the prosperity of the 1920s, they should receive full blame for the depression. Roosevelt was spectacularly successful at this. .u6ea9734419b17745d960e1d07460b976 , .u6ea9734419b17745d960e1d07460b976 .postImageUrl , .u6ea9734419b17745d960e1d07460b976 .centered-text-area { min-height: 80px; position: relative; } .u6ea9734419b17745d960e1d07460b976 , .u6ea9734419b17745d960e1d07460b976:hover , .u6ea9734419b17745d960e1d07460b976:visited , .u6ea9734419b17745d960e1d07460b976:active { border:0!important; } .u6ea9734419b17745d960e1d07460b976 .clearfix:after { content: ""; display: table; clear: both; } .u6ea9734419b17745d960e1d07460b976 { display: block; transition: background-color 250ms; webkit-transition: background-color 250ms; width: 100%; opacity: 1; transition: opacity 250ms; webkit-transition: opacity 250ms; background-color: #95A5A6; } .u6ea9734419b17745d960e1d07460b976:active , .u6ea9734419b17745d960e1d07460b976:hover { opacity: 1; transition: opacity 250ms; webkit-transition: opacity 250ms; background-color: #2C3E50; } .u6ea9734419b17745d960e1d07460b976 .centered-text-area { width: 100%; position: relative ; } .u6ea9734419b17745d960e1d07460b976 .ctaText { border-bottom: 0 solid #fff; color: #2980B9; font-size: 16px; font-weight: bold; margin: 0; padding: 0; text-decoration: underline; } .u6ea9734419b17745d960e1d07460b976 .postTitle { color: #FFFFFF; font-size: 16px; font-weight: 600; margin: 0; padding: 0; width: 100%; } .u6ea9734419b17745d960e1d07460b976 .ctaButton { background-color: #7F8C8D!important; color: #2980B9; border: none; border-radius: 3px; box-shadow: none; font-size: 14px; font-weight: bold; line-height: 26px; moz-border-radius: 3px; text-align: center; text-decoration: none; text-shadow: none; width: 80px; min-height: 80px; background: url(https://artscolumbia.org/wp-content/plugins/intelly-related-posts/assets/images/simple-arrow.png)no-repeat; position: absolute; right: 0; top: 0; } .u6ea9734419b17745d960e1d07460b976:hover .ctaButton { background-color: #34495E!important; } .u6ea9734419b17745d960e1d07460b976 .centered-text { display: table; height: 80px; padding-left : 18px; top: 0; } .u6ea9734419b17745d960e1d07460b976 .u6ea9734419b17745d960e1d07460b976-content { display: table-cell; margin: 0; padding: 0; padding-right: 108px; position: relative; vertical-align: middle; width: 100%; } .u6ea9734419b17745d960e1d07460b976:after { content: ""; display: block; clear: both; } READ: Bartleby The Scrivener EssayRoosevelts first inaugural address, with its pledge to make war upon the depression and its ringing phrase, we have nothing to fear but fear itself, brought a new style to the U.S. presidency. Not long after being in office Roosevelt started a new program, that would hopefully get the U.S. out of the depression called the New Deal. After many great accomplishments in office Roosevelt was re-elected in 1936 to his second term, after this term most expected him not to run again in 1940, out of tradition that no president before him served no more than two terms, but he ran anyway and won by a fair margin. In 1938 Hitler of Germany started WWII by invading Poland, and Roosevelt knew it wouldnt be long until the U.S. was brought into the war, so he started supplying the Allies with weapons and ships on a lend-lease program. Then on December the 7th 1941, Japan bombed Pearl Harbor and brought the U.S. into the war. Roosevelt did not live to see the end of World War II. During the war years he had not appeared often in public, but during his campaign for a fourth term in 1944 many who saw him said that he looked pale, thin, and old. The election, which resulted in his victory over New York Governor Thomas E. Dewey, was a strain on the president, as was the long trip to Yalta. In the early spring of 1945 he went to Warm Springs, Georgia, in an effort to recapture his lost energy. There he died of a massive cerebral hemorrhage on April 12, 1945. Harry Truman took the oath of office to become president the same day.

Nickel complex from Schiff base ligand free essay sample

We perform two separate reactions in this experiment in order to obtain Schiff Base Ligand that will substitute the ligands of a nickel hydrated complex. Like the majority of the common transition metals, during the reaction of nickel metal reaction, nickel metals tend to form an ion with a charge of 2+. This helps it to form complexes because of the empty orbitals it has around it. This nature of the metals allows it to bond with compounds through lone pairs, which is scientifically known as the dative bonding. On the second part of this experiment we react the Schiff base ligand with hydrated nickel complex, this will allow us to form new nickel complex which is known as. We do this through condensation and substitution from the hydrated nickel complex. Results and discussion During the mixing of pyrrole-2-aldehyde with ethanol and 1,3-diaminopropane we obtain a colourless solution. As it is being heated under reflux, colour change is observed, the solution starts to change into orange-red solution. This is due to the fact that nickel ions are being suspended in the solution. After 4 minutes of heating under reflux, we finally cool it for 1 hour 30 minutes in ice bath, after this period of time yellow crystals start to form at the bottom of the round bottomed flask. After the filtering of these crystals, the remain yellow and after being rinsed with diethyl ether they change into a light yellow colour. We than dissolve these crystals in warm ethanol and the resultant solution turns slightly yellow. The solution immediately turns brick red because of the precipitate that is present, suspended in the solution. The solution remains brick red after the addition of the the sodium carbonate, but as I stir the precipitate intensifies. The first filtered crystals are pasty. When i redissolve them in dichloromethane they form a cleared solution. Using the rotary evaporator to evaporate the dichloromethane and petroleum ether we obtain dark red crystals. Percentage yield of Schiff base ligand: Pyrrole-2aldehyde Molar mass= 14+16+(12. 015)+(1. 0085) =95. 09 g. mol-1 n = = =9. 9910-3 mol 1,3-diaminopropane Molar mass=(142)+(1. 00810)+(12. 013) =74. 11 g. mol-1 density = 0. 88=m= 0. 352g n = = =4. 7510-3 mol Therefore the ratios: Pyrrole-2-aldehyde : 1,3-diaminopropane 2:1 9. 9910-3: x x = 4. 99510-3 mol Table1: Theoretical mass calculations of the Schiff Base Ligand Moles Pyrrole-2-aldehyde 1,3-diaminopropane Schiff Base Ligand Initial moles 9. 99? 10-3 4. 75? 10-3 0 Reacted moles 4. 75? 10-3 4. 75? 10-3 0 Moles produced or left 5. 293? 10-3 0 4. 75? 10-3 So we have 1,3-diaminopropane as our limitin g reagent. Thus the theoretical yield is: Molar mass of Schiff Base Ligand= 228. 298g/mol Mass= No. of moles ? molar mass =4. 75? 10-3? 228.298 =1. 08g Thus the percentage yield: Actual mass = 0. 767g %yield = = =71. 01% The theoretical and percentage yield of Nickel (II) Complex from Schiff Base Ligand Nickel acetate Molar mass= (168)+(124)+(1. 00814)+58. 69 =200. 802 g. mol-1 n = = =2. 4910-3mol Schiff base ligand Molar mass=(1213)+(1. 00816)+(144) =228. 128 g. mol-1 n = = =1. 5810-3mol Therefore the ratios: Nickel acetate : Schiff base ligand 1:1 2. 4910-3 : x X = 2. 4910-3 mol Thus the limiting reagent is Schiff base ligand Table1: Theoretical mass calculations of the nickel complex Moles Nickel acetate Schiff base ligand Nickel complex Initial moles 2. 49? 10-3 1. 58? 10-3 0 Reacted moles 1. 58? 10-3 1. 58? 10-3 0 Moles produced or left 9. 1? 10-4 0 9. 1? 10-4 Molar mass of nickel complex= 284. 972g/mol Mass= No. of moles ? molar mass =9. 1? 10-4? 284. 972 =0. 26g Thus the percentage yield: Actual mass = 0. 1g %yield = = =38. 46% Note: from left to right on the spectrum signal ? (ppm) Intergral Multiplicity Assignment 1 9. 83 2 Broad singlet A 2 8. 03 2 Singlet B 3 6. 85 2 Singlet C 4 6. 46 2 Doublet D 5 6. 22 2 Triplet E 6 3. 62 4 Triplet F 7 1. 98 2 Pentet G Table 1: results from the spectrum of the Schiff base ligand. signal ? (ppm) Intergral Multiplicity Assignment 1 6. 9 2 Triplet E 2 6. 6 2 Doublet D 3 6. 1 2 Singlet C 4 3. 2 4 Triplet B 5 1. 8 1 Quintet A 6 1. 5 1 Quintet A 7 7. 2 2 Doublet F Table 2: results from the spectrum of the nickel complex Schiff Base ligand + [Ni(OCOH)2 Â · 4H2O] Nickel complex Ni(OCOCH3)2. 4H2O + C13H16N4 [Ni(C13H14N4)] + (CH3COOH)2 + 4H2O This implies that the Schiff Base ligand and the Nickel complex have a 1 : 1 ratio in the reaction. The structure of the product that forms is: 2. So we can classify the Schiff Base ligand as tetradentate ligand because one ligand donates four lone pairs to the nickel ion. Thus the nickel ion has a coordinate number of four, which constitute the square planar shape, nickel being bonded to the Nitrogens that have the lone pairs to fill the empty shell of the nickel ion. 3. On the Schiff base ligand, we get a spectrum that has 7 signals because of the extra hydrogens bonded to nitrogens compared to the nickel complex but on the nickel complex, we get 6 signals because the hydrogens that were bonded to the nitrogens were removed during the chelation.4(a). 4(b). 4(c). 5. Conclusion Thus it is visible that how much nickel complex we have, depends on how much Schiff base ligand we have. The more Schiff base ligand we produce, the more possible it is to obtain higher yield of nickel complex, since they react on a 1 : 1 ratio. The yield of the Schiff base ligand was 0. 36g and from this ligand 0. 1g of nickel complex was yielded using 0. 5g of nickel acetate.